Target: 10 Questions in 10 minutes

An IB Chemistry data booklet is helpful

1. What is the empirical formula of a compound containing 79.9% by mass of carbon and 20.1% by mass of hydrogen?

  • A.   CH2
  • B.   CH3
  • C.   CH4
  • D.   C2H3
2. Metal X forms an oxide which contains 32% by mass of oxygen. Metal X has a relative atomic mass of 51. What is the empirical formula of the oxide?
  • A.   XO2
  • B.   X2O
  • C.   XO3
  • D.   X2O3

3. A sample of an oxide of sulfur was analysed and found to contain 1.6g of sulfur and 2.4g of oxygen. What is its empirical formula?

  • A.   S2O3
  • B.   SO3
  • C.   SO2
  • D.   S2O
4. Melamine has an empirical formula of CH2N2 and its molecular mass is 126 g mol-1. What is the molecular formula of melamine? melamine plates and bowl
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  • A.   CH2N2
  • B.   C2H4N4
  • C.   C3H6N6
  • D.   C4H8N5
5. 5.0g of an oxide of chromium was formed from 2.6g of chromium. What is the empirical formula of this oxide?
  • A.   CrO
  • B.   CrO3
  • C.   CrO6
  • D.   Cr2O3

6. Which of the following compounds has/have the empirical formula CH2O?

I. C6H12O6
II. CH3COOH
III. C12H24O11
  • A.   I only
  • B.   I and II only
  • C.   II and III only
  • D.   I, II and III
7. When 0.25 mol of a hydrocarbon burns completely in oxygen, 44.0g of carbon dioxide and 22.53g of water are produced. What is the molecular formula for the hydrocarbon?
  • A.   C2H5
  • B.   C4H8
  • C.   C4H10
  • D.   C4H20
8. How many moles of water of crystallization are combined with each mole of calcium sulfate if 2.72g of anhydrous calcium sulfate (Mr = 136g mol-1) is formed when 3.44g of hydrated calcium sulfate is heated to constant mass?
  • A.   1
  • B.   2
  • C.   3
  • D.   4
9. What is the empirical formula of a hydrocarbon which produced 4.40g of carbon dioxide and 2.70g of water on complete combustion?
  • A.   CH
  • B.   CH2
  • C.   CH3
  • D.   C2H3
10. Which of the following compounds, used in the production of fertilizers, has the highest percentage by mass of nitrogen? bags of fertiliser
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  • A.   NH3
  • B.   NH4NO3
  • C.   CO(NH2)2
  • D.   (NH4)2SO4
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Question 1:

To determine the empirical formula of a compound containing 79.9% carbon and 20.1% hydrogen by mass, follow these steps:

  1. Assume a 100 g sample:

    • Mass of carbon = 79.9 g

    • Mass of hydrogen = 20.1 g

  2. Convert masses to moles:

    • Moles of carbon = 79.9/12.01≈6.6536 mol

    • Moles of hydrogen = 20.1/1.008≈19.9405 mol

  3. Find the simplest mole ratio:

    • Divide each by the smallest number of moles (which is carbon, 6.6536):

      • Carbon: 6.6536 / 6.6536=1

      • Hydrogen: 19.9405 / 6.6536≈2.996≈3

  4. Write the empirical formula:

    • The ratio is C : H = 1 : 3, so the empirical formula is CH₃.

Answer: B. CH₃


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Question 2:

Assume a 100 g sample of the oxide:

Now, convert masses to moles:

Find the simplest mole ratio by dividing both by the smaller number of moles (which is 1.3333):

To get whole numbers, multiply both by 2:

Thus, the empirical formula is X₂O₃.

Answer: D. X₂O₃


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Question 3:

To determine the empirical formula of the oxide of sulfur given:

Follow these steps:

  1. Convert masses to moles:

    • Molar mass of sulfur (S) = 32 g/mol

    • Molar mass of oxygen (O) = 16 g/mol

    • Moles of S = 1.6/32=0.05 mol

    • Moles of O = 2.4/16=0.15 mol

  2. Find the simplest mole ratio:

    • Divide both by the smallest number of moles (which is 0.05):

      • S: 0.05/0.05=1

      • O: 0.15/0.05=3

  3. Write the empirical formula:

    • The ratio is S : O = 1 : 3, so the empirical formula is SO₃.

Answer: B. SO₃


*These A.I. responses have been individually checked to ensure they match the accepted answer, but explanations may still be incorrect. Responses may give guidance but the A.I. might not be able to answer the question! This is particularly the case for questions based on diagrams, which the A.I. typically cannot interpret.
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Question 4:

To find the molecular formula of melamine given:

Follow these steps:

  1. Calculate the empirical formula mass:

    • Carbon (C): 12 g/mol × 1 = 12 g/mol

    • Hydrogen (H): 1 g/mol × 2 = 2 g/mol

    • Nitrogen (N): 14 g/mol × 2 = 28 g/mol

    • Total empirical mass = 12 + 2 + 28 = 42 g/mol

  2. Determine the multiple (n):

    • n = Molecular mass / Empirical mass = 126 / 42 = 3

  3. Multiply the empirical formula by n:

    • Molecular formula = (CH₂N₂) × 3 = C₃H₆N₆

Answer: C. C₃H₆N₆


*These A.I. responses have been individually checked to ensure they match the accepted answer, but explanations may still be incorrect. Responses may give guidance but the A.I. might not be able to answer the question! This is particularly the case for questions based on diagrams, which the A.I. typically cannot interpret.
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Question 5:

To determine the empirical formula of the oxide of chromium:

Given:

First, find the mass of oxygen:

Now, convert masses to moles:

Find the simplest mole ratio by dividing both by the smallest number of moles (0.05):

The ratio is Cr : O = 1 : 3, so the empirical formula is CrO₃.

Answer: B. CrO₃


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Question 6:

To determine which compounds have the empirical formula CH₂O, we need to simplify each molecular formula to its simplest whole-number ratio.

Recall: The empirical formula CH₂O has a ratio of C : H : O = 1 : 2 : 1.

Let's analyze each compound:

I. C₆H₁₂O₆

II. CH₃COOH (which is C₂H₄O₂)

III. C₁₂H₂₄O₁₁

Therefore, only I and II have the empirical formula CH₂O.

Answer: B. I and II only


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Question 7:

To determine the molecular formula of the hydrocarbon, let's analyze the combustion reaction:

The hydrocarbon (CxHy) burns in oxygen to produce CO₂ and H₂O:

CxHy + O₂ → xCO₂ + (y/2)H₂O

Given:

Step 1: Find the moles of CO₂ and H₂O produced

Step 2: Relate these to the moles of hydrocarbon
Since 0.25 mol of hydrocarbon produces:

Step 3: Determine the molecular formula
The hydrocarbon has the formula C₄H₁₀.

Answer: C. C₄H₁₀


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Question 8:

To determine the number of moles of water of crystallization (n) in hydrated calcium sulfate
(CaSO₄.nH₂O), follow these steps:

Given:

  • Mass of anhydrous CaSO₄after heating = 2.72 g

  • Molar mass of CaSO₄ = 136 g/mol

  • Mass of hydrated salt before heating = 3.44 g

Step 1: Calculate the mass of water lost:

Mass of water=Mass of hydrated salt−Mass of anhydrous salt=3.44 g−2.72 g=0.72 g

Step 2: Calculate moles of anhydrous CaSO₄:

Moles of CaSO₄=2.72/136=0.02 mol

Step 3: Calculate moles of water lost:

  • Molar mass of H₂O = 18 g/mol

Moles of H₂O=0.72/18=0.04 mol

Step 4: Find the ratio of moles of water to moles of CaSO₄:

n=(moles of H₂O)/(moles of CaSO₄)=0.04/0.02=2

Thus, the formula of the hydrated salt is CaSO₄.H₂O

Answer: B. 2


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Question 9:

To determine the empirical formula of the hydrocarbon from its combustion products:

Given:

Step 1: Find the moles of carbon and hydrogen in the hydrocarbon

Step 2: Find the simplest mole ratio (C : H)

So, the empirical formula is CH₃.

Answer: C. CH₃


*These A.I. responses have been individually checked to ensure they match the accepted answer, but explanations may still be incorrect. Responses may give guidance but the A.I. might not be able to answer the question! This is particularly the case for questions based on diagrams, which the A.I. typically cannot interpret.
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Question 10:

To determine which compound has the highest percentage by mass of nitrogen, we'll calculate the mass percentage of nitrogen in each option.

A. NH₃ (Ammonia)

B. NH₄NO₃ (Ammonium nitrate)

C. CO(NH₂)₂ (Urea)

D. (NH₄)₂SO₄ (Ammonium sulfate)

Comparing the percentages:

NH₃ has the highest percentage by mass of nitrogen.

Answer: A. NH₃


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