Target: 10 Questions in 10 minutes

An IB Chemistry data booklet is helpful

1. Which of the following statements about mixtures is true?
  • A.   Mixtures have a fixed composition
  • B.   Differences in physical properties are used to separate components of a mixture
  • C.   The components in a mixture are chemically combined
  • D.   Mixtures can be represented by a chemical formula
2. Which of the following is NOT a homogeneous mixture?
  • A.   oil and water
  • B.   stainless steel
  • C.   ethanol and water
  • D.   unpolluted air
3. Select an appropriate method for obtaining crystals of potassium chloride from its aqueous solution:
  • A. simple distillation
  • B. filtration
  • C. paper chromatography
  • D. solvation
4. Thin layer chromatography can be used to analyse amino acids in the pharmaceutical industry. Which of the following amino acids has an Rf value of 0.5?

amino acid chromatography

 
  • A. amino acid A
  • B. amino acid B
  • C. amino acid C
  • D. amino acid D
5. Which statement describes a compound?
  • A.   a compound consists of atoms of the same element.
  • B.   in a compound, the elements are physically bonded together.
  • C.   in a compound, the elements are present in a fixed ratio.
  • D.   the elements in a compound can be separated by physical methods.
6. Bromine has a melting point of -7.05oC and a boiling point of 58.8oC . At which temperature is bromine a liquid?
  • A.   200 K
  • B.   250 K
  • C.   300 K
  • D.   350 K

 

7. What is the name given to the change of state represented by the following equation?

   CO2(g) ⇌ CO2(s)

  • A.   condensation
  • B.   deposition
  • C.   freezing
  • D.   sublimation

8. Which of the following occur as steam condenses to water?

I. The kinetic energy of the particles increases
II. The distance between the particles increases
III. The temperature remains constant
 
  • A.   I and II only
  • B.   I and III only
  • C.   II and III only
  • D.   III only

9. Which of the following graphs best represents the cooling curve when a pure substance with a melting point of 50°C is cooled from 75°C to room temperature?

cooling curve graphs x4

10. Which of these changes of state is endothermic?
  • A.   H2O(g)    H2O(l)
  • B.   I2(s) I2(g)
  • C.   Na(l)    Na(s)
  • D.   2C6H6(l) + 15O2(g)    12CO2(g) + 6H2O(l)
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Question 1:

Let's evaluate each option:

A. Mixtures have a fixed composition – This is false. Mixtures can have varying compositions (e.g., saltwater can have different amounts of salt).

B. Differences in physical properties are used to separate components of a mixture – This is true. For example, filtration uses differences in particle size, distillation uses differences in boiling points, and chromatography uses differences in solubility or adhesion.

C. The components in a mixture are chemically combined – This is false. In a mixture, the components are physically combined and can be separated by physical means. Chemical combinations occur in compounds, not mixtures.

D. Mixtures can be represented by a chemical formula – This is false. Only pure substances (elements and compounds) have chemical formulas. Mixtures do not have a fixed ratio of components and thus cannot be represented by a single formula.

Therefore, the correct statement is B.


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Question 2:

Let's evaluate each option to determine which is NOT a homogeneous mixture:

A. Oil and water – This is a heterogeneous mixture. Oil and water do not mix uniformly; they separate into distinct layers due to differences in polarity and density.

B. Stainless steel – This is a homogeneous mixture (specifically, a solid solution). It is an alloy of iron, carbon, chromium, and other elements, with a uniform composition.

C. Ethanol and water – This is a homogeneous mixture. Ethanol and water are miscible and form a uniform solution.

D. Unpolluted air – This is a homogeneous mixture. Air is a uniform mixture of gases (mainly nitrogen, oxygen, argon, etc.).

Therefore, the option that is NOT a homogeneous mixture is A. oil and water.


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Question 3:

The correct answer is A. simple distillation.

To obtain crystals of a soluble solid like potassium chloride (KCl) from an aqueous solution, the most common method is crystallization by evaporation. This involves gently heating the solution to evaporate the water, which causes the solution to become saturated and then supersaturated, forcing the solute to precipitate out as crystals.

However, among the given options, simple distillation is the only one that can technically achieve this result. In simple distillation, the solvent (water) is boiled off and collected separately, leaving the non-volatile solid solute (KCl) behind in the distillation flask.

Filtration (B) is for separating insoluble solids.

Paper chromatography (C) is for analyzing mixtures, not for obtaining large quantities of a substance.

Solvation (D) is the process of dissolving, which is the opposite of the desired outcome.


*These A.I. responses have been individually checked to ensure they match the accepted answer, but explanations may still be incorrect. Responses may give guidance but the A.I. might not be able to answer the question! This is particularly the case for questions based on diagrams, which the A.I. typically cannot interpret.
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Question 4:

To determine which amino acid has an Rf value of 0.5, we need to calculate the Rf value for each amino acid and compare it to 0.5.

The Rf (retardation factor) value is calculated using the formula:

Rf=(distance travelled by the amino acid) ÷ (distance travelled by the solvent front

Given:

Now, calculate the Rf value for each amino acid:

For Acid A:

Rf=6/7≈0.857

For Acid B:

Rf = 4.5/7≈0.643

For Acid C:

Rf=3.5/7=0.5

For Acid D:

Rf=2.5/7≈0.357

From the calculations, Acid C has an Rf value of exactly 0.5.

Answer: Acid C has an Rf value of 0.5.


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Question 5:

Let's evaluate each option to determine which statement correctly describes a compound:

The correct statement is C: In a compound, the elements are present in a fixed ratio.


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Question 6:

To determine at which temperature bromine is a liquid, we need to consider its melting and boiling points:

Bromine is in the liquid state between these two temperatures. That is, above -7.05°C and below 58.8°C.

Now, we need to check which of the given options (in Kelvin) falls within this range. First, convert the melting and boiling points to Kelvin:

So, bromine is a liquid between about 266 K and 332 K.

Now, evaluate the options:

Therefore, at 300 K, bromine is a liquid.

Answer: C. 300 K


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Question 7:

The equation given is:

 CO2(g) ⇌ CO2(s)

This represents a direct change from a gas to a solid without passing through the liquid state. This process is known as deposition.

Now, let's review the options:

In this case, the equation shows gas to solid, which is deposition. Note that the reverse process (solid to gas) is sublimation, but here the arrow points from gas to solid.

Answer: B. deposition


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Question 8:

When steam condenses to water, it is a phase change from gas to liquid. Let's evaluate each statement:

I. The kinetic energy of the particles increases:
This is false. During condensation, the particles are losing energy as they transition from gas to liquid. The kinetic energy (related to motion) decreases because the particles slow down.

II. The distance between the particles increases:
This is false. In a gas, particles are far apart; in a liquid, they are closer together. So, the distance between particles decreases during condensation.

III. The temperature remains constant:
This is true. During a phase change (like condensation), the temperature remains constant because the energy being removed is used to overcome intermolecular forces rather than to change the kinetic energy of the particles.

Therefore, only III is correct.

Answer: D. III only


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Question 9:

The graph in option A correctly represents the cooling curve of a pure substance. This is because a pure substance has a single, distinct melting and freezing point.

Here's a breakdown of the cooling process represented in the graph:

The substance starts as a liquid at 75°C and cools down, which is shown by the downward-sloping line.

When the substance reaches its freezing point of 50°C, it begins to change from a liquid to a solid. During this phase change, energy is released as latent heat of fusion, which keeps the temperature constant until all of the substance has solidified. This is represented by the flat, horizontal section of the graph at 50°C.

Once the substance is completely solid, it continues to cool down to room temperature, which is shown by the final downward-sloping line.

The graph in option B is incorrect because it shows a continuous decrease in temperature. This is characteristic of a mixture or an impure substance, which does not have a fixed freezing point.


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Question 10:

To determine which change of state is endothermic, recall that endothermic processes absorb energy (heat) from the surroundings. Phase changes that require energy input are endothermic.

Let's analyze each option:

A. H₂O(g) → H₂O(l)
This is condensation (gas to liquid). Condensation releases energy (exothermic).

B. I₂(s) → I₂(g)
This is sublimation (solid to gas). Sublimation requires energy to break intermolecular forces and is endothermic.

C. Na(l) → Na(s)
This is freezing (liquid to solid). Freezing releases energy (exothermic).

D. 2C₆H₆(l) + 15O₂(g) → 12CO₂(g) + 6H₂O(l)
This is a combustion reaction (burning of benzene). Combustion reactions are exothermic (they release heat).

Therefore, only option B (I₂(s) → I₂(g)) is endothermic.


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